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Spectacular Spiderman The Complete Series These adventures find our hero tackling more Super Villains both old and new, including Chameleon, Venom and the Sinister Six Electro, Doctor Octopus, Vulture, Sandman, Rhino and Shocker. While these criminals are almost more than Spidey can handle, his real struggle becomes an internal one. The stress is enough to drive a high school Super Hero over the edge, but making mistakes and learning lessons is all in a days work for the Spectacular Spider-Man (TM).