No. It can only connect to one item at a time. For example, when I’m connected to my laptop I can’t answer the phone and it all be on the headphones. The switching can be annoying.
Not one of your questions, but I still believe it’s important you know. The headphones need to be gently stretched. They are WAY too tight! Honestly I think it’s worth buying the more expensive Beats models, not the Solos, or just buy the wireless in-ears. I semi regret my Solo purchase.