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No. It will seek out any files in one of the top streaming services (Google Play Music, Pandora, Spotify, YouTube Music, for example) and play songs available through one of those services. In order for it to a) identify a drive, b) search that drive, c) identify songs based on a voice command, and d) play them, you would need to set up a recipe through IFTTT, and Google Home has next to no integration with IFTTT other than a listing on their site. Google's integration is minimal, even with their own apps like Keep, Calendar, and Google Now. Features like what you're asking about here are at least a year away, so hang on to your cash.
Sorry, there was a problem. Please try again later.Not currently. They might be able to add that as a feature though.
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