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Hello, We can't ever confirm that using this memory with other existing memory you'd be able to use without issues. That being said, your system would use 1600MHz RAM: https://everymac.com/systems/apple/imac/specs/imac-core-i5-3.5-27-inch-aluminum-retina-5k-late-2014-specs.html If you have anything else we can help with, please reach out: support.corsair.com -Art
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