A:Answer Not with this unit. In general this is a bluetooth receiver, not a transmitter. Receivers are good for pairing with phones, tablets, and computers. In order to send audio to a bluetooth headphone, earbuds, or speakers you will want to use a Bluetooth transmitter. This way the audio from your TV connects directly to your Transmitter and then the Transmitter send the audio (via Bluetooth) to your headphones. I highly recommend our ABC01F which can operate in both RX (receiving) and TX (for transmitting) modes. You can also get our ABT05F. If you TV has Optical audio OUT you may want to consider the ABC02F or the ABCD54F. Those units have the optical connectors and come with the optical cable.